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Substituent effects on the 15N NMR Parameters of Azoles

✍ Scribed by ROSA MARÍA CLARAMUNT; DIONISIA SANZ; CONCEPCIÓN LÓPEZ; JOSÉ ANTONIO JIMÉNEZ; MARÍA LUISA JIMENO*; JOSÉ ELGUERO; ALAIN FRUCHIER

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
456 KB
Volume
35
Category
Article
ISSN
0749-1581

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✦ Synopsis

The 15N chemical shifts and a large collection of coupling constants pertaining to azoles have been gathered from the literature. To complete this collection and to check some anomalies, the spectra of 14 compounds in several solvents were recorded again and 31 compounds were studied for the first time ; in all, data for 420 compounds (pyrroles, imidazoles, pyrazoles, triazoles, tetrazoles, indoles, benzimidazoles, indazoles, benzotriazoles and carbazoles) are reported. Additive models are used to discuss the substituent chemical shifts.

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