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A study of the mechanisms and kinetics of the molten state reaction of non-catalyzed cyanate and epoxy-cyanate systems

✍ Scribed by Marie-Florence Grenier-Loustalot; Christine Lartigau; Philippe Grenier


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
834 KB
Volume
31
Category
Article
ISSN
0014-3057

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πŸ“œ SIMILAR VOLUMES


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✍ Marie-Florence Grenier-Loustalot; Christine Lartigau πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 347 KB

Based on an FT-IR and 13 C-NMR spectroscopic study using model compounds, we previously proposed an epoxy-cyanate coreaction path in the molten state, by identifying all chemical species and their role in the reaction mixture. These data were then applied to difunctional systems involving diglycidyl

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## Abstract A general protocol for the cyanation of aryl halides with the nontoxic cyanide source K~4~[Fe(CN)~6~] using copper catalysis and a ligand system based on 1‐alkylimidazoles is presented. The advantages of this system are the high selectivity, a unique substrate range, easy handling, and