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A study of the mechanism of rhodium/phosphine-catalyzed hydroformylation: use of 1,1′-bis(diarylphosphino)ferrocene ligands

✍ Scribed by Jerry D. Unruh; Jack R. Christenson


Publisher
Elsevier Science
Year
1982
Weight
889 KB
Volume
14
Category
Article
ISSN
0304-5102

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Selectivity of Rhodium-Catalyzed Hydrofo
✍ Ard C. J. Koeken; Michiel C. A. van Vliet; Leo J. P. van den Broeke; Berth-Jan D 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 377 KB 👁 1 views

## Abstract The regioselectivity of catalysts generated __in situ__ from dicarbonyl rhodium(I)(2,4‐pentanedione) and trifluoromethyl‐substituted triphenylphosphine ligands has been evaluated during the hydroformylation of 1‐octene. The influence of batch or semi‐batch operation, the solvent, and th