✦ LIBER ✦

A study of the mechanism and kinetics of the reaction of O(3P) atoms with propane

✍ Scribed by Alan B. Harker; C. S. Burton

Publisher: John Wiley and Sons
Year: 1975
Tongue: English
Weight: 525 KB
Volume: 7
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550070610

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✦ Synopsis

Abstract

The mechanism and kinetics of the reaction of O(^3^P) atoms with propane were investigated using molecular modulation spectroscopy, with the O(^3^P) atoms being generated by the Hg photosensitized decomposition of N~2~O. The absorption spectrum of the X^2^II~3/2~ state of OH was observed in the ultraviolet between 307 and 309 nm, and it was confirmed that OH was the product of the O(^3^P) reaction with propane. The rate constants for the reactions of O(^3^P) and OH with propane were determined to be 3.9±0.7±10^10^ and 1.19±0.05±10^12^ cm^3^/mole·sec, respectively, at T=56±5°C.

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