𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A study of the isomerization of acetonitrile at high temperatures

✍ Scribed by Ko Saito; Terumitsu Kakumoto; Ichiro Murakami

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
330 KB
Volume
110
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The thermal isomerization of acetonitrile to methyl isocyanide was investigated in the temperature range 1600-2100 K behind reflected shock waves. An Arrhenius expression for the low-pressure rate constant was obtained as, X-o/[Ar] = 10'3-40 esp(-159 kJ mol-'/f?7') cm3 moT' s-'. By connecting with the data for the reverse reaction at lower temperatures, the temperature dependences of the weak collision parameters, pc and (AE). were found to be large.

πŸ“œ SIMILAR VOLUMES

The isomerization of cycloheptatriene at
The isomerization of cycloheptatriene at high temperatures
✍ Brendan J. Gaynor; Robert G. Gilbert; Keith D. King; John C. Mackie πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 583 KB

## Abstract The isomerization of cycloheptatriene at high temperatures (800–1250Β°K) has been studied experimentally using a shock tube at high pressures and by very low‐pressure pyrolysis in the intermediate‐pressure region (the first direct use of the latter technique for an isomerization). Rate c

Thermal reactions of acetonitrile at hig
Thermal reactions of acetonitrile at high temperatures. Pyrolysis behind reflected shocks
✍ Assa Lifshitz; Ahuva Moran; Shimon Bidani πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 876 KB

The thermal decomposition of acetonitrile was studied behind reflected shocks in a single pulse shock tube over the temperature range 1350-1950 K at overall densities of approximately 3 x mol/cc. Methane and hydrogen cyanide are the major reaction products. They are formed by an attack of H and CH,

A shock tube study of the CH2O + NO2 rea
A shock tube study of the CH2O + NO2 reaction at high temperatures
✍ Chin-Yu Lin; Hung-Tai Wang; M. C. Lin; C. F. Melius πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 867 KB

## Abstract The reaction of CH~2~O with NO~2~ has been studied with a shock tube equipped with two stabilized ew CO lasers. The production of CO, NO, and H~2~O has been monitored with the CO lasers in the temperature range of 1140–1650 K using three different Ar‐diluted CH~2~O‐NO~2~ mixtures. Kinet

Study of the double layer at the Hg/aque
Study of the double layer at the Hg/aqueous KCl interface at high temperatures
✍ L.B. Kriksunov; O.A. Semenikhin; L.V. Bunakova πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 750 KB

The differential capacity-potential relations for the mercury electrode in diluted aqueous KC1 solutions at the temperatures from ambient to 300Β°C were obtained. The values of zero charge potential of mercury at different temperatures were derived as the potential of the capacitance minimum. It was