✦ LIBER ✦

A shock tube study of the CH2O + NO2 reaction at high temperatures

✍ Scribed by Chin-Yu Lin; Hung-Tai Wang; M. C. Lin; C. F. Melius

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 867 KB
Volume: 22
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550220504

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The reaction of CH~2~O with NO~2~ has been studied with a shock tube equipped with two stabilized ew CO lasers. The production of CO, NO, and H~2~O has been monitored with the CO lasers in the temperature range of 1140–1650 K using three different Ar‐diluted CH~2~O‐NO~2~ mixtures. Kinetic modeling and sensitivity analysis of the observed CO, NO, and H~2~O production profiles over the entire range of reaction conditions employed indicate that the bimolecular metathetical reaction, NO~2~ + CH~2~O → HONO + CHO (1) affects most strongly the yields of these products. Combination of the kinetically modeled values of 𝓀~1~ with those obtained recently from a low temperature pyrolytic study, ref. [8], leads to
for the broad temperature range of 300–2000 K.

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