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A Study of the Double Fries Rearrangement 1,2

✍ Scribed by Thomas, Forrest D.; Shamma, Maurice; Fernelius, W. Conard


Book ID
126146383
Publisher
American Chemical Society
Year
1958
Tongue
English
Weight
510 KB
Volume
80
Category
Article
ISSN
0002-7863

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The fries rearrangement of 1-naphthyl ac
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## Abstract The rearrangement of 1‐naphthyl acetate in nitrobenzene solution, catalysed by aluminium chloride, to give 2‐ and 4‐acetylnaphthol, appears to be intramolecular in nature. A mechanism to account for the experimental results is proposed. While the main product is the __p__‐hydroxy‐ketone