A Study of the Benzyl Free Radical and Substituted Benzyl Free Radicals
โ Scribed by Hodgkins, Joe E.; Megarity, E. Dennis
- Book ID
- 127305448
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 618 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
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Al~tract---Methyl a-p-chlorobenzylacrylate and methyl :t-p-methoxybenzylacrylate were synthesized from dimethylmalonate by well known organic reactions. Both monomers were polymerizcd by a free-radical mechanism in benzene and their ceiling temperaturc determined. Comparison of the ceiling temperatu
Fluorescence lifetimes of C~KSCH~,O-,'~-,~-DC~H~CII\_~, C6HsCD&'C&~CHi, and CeD,CD+ have been me&wed at 77 K in rigid piasses. Very long decay times are obkerwd for aU the radicals. There is a dramatic deuterium af-.' feet upon ring deuceration; alkyl deuteration lengthens the lifetime if :%e phenyl