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A study of C–35Cl coupling constants and 35Cl relaxation times through 13C relaxation in the rotating frame

✍ Scribed by Vladimír Mlynárik

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
227 KB
Volume
22
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Values of one‐bond J(C^35^ Cl) and T~1~(^35^Cl) were determined for small chlorine‐containing molecules through ^13^C scalar relaxation in the rotating frame. A method is suggested for evaluating the contribution of scalar relaxation which eliminates experimental imperfections. The magnitude of J(C^35^Cl) seems to be influenced by the same factors as J(CF) values. The differences in ^35^Cl relaxation times are rationalized in terms of the molecular reorientation time.

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