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A stereospecific synthesis of functionalised cyclopentene derivatives. New principle of carbon-chain lengthening.

✍ Scribed by Eric Cossement; Robert Binamé; Léon Ghosez

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
173 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

Ketenes bearing a-carbanion-stabilizing substituents are useful synthetic intermediates 192 offering the interesting possibility of effecting the position-and stereospecific addition of two carbon-chains to an olefinic substrate (scheme 1).

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