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A Stereospecific Access to Allylic Systems Using Rhodium(II)−Vinyl Carbenoid Insertion into Si−H, O−H, and N−H Bonds

✍ Scribed by Bulugahapitiya, Priyadarshanie; Landais, Yannick; Parra-Rapado, Liliana; Planchenault, Denis; Weber, Valéry


Book ID
125442115
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
478 KB
Volume
62
Category
Article
ISSN
0022-3263

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Rhodium(II) (S)-N-(arylsulfonyl)prolinat
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Allylsilanes or benzylsilanes of high enantiomeric purity (77-95% ee) are formed from the rhodium(lI) (S)-N-[p-(dodecylphenyl)sulfonyl]prolinate (1) catalyzed decomposition of vinyldiazomethanes or phenyMiazomethanes in the presence of dimethylphenylsilane (3).