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A stereoselective route to 2-(phenylthio)-1,3-butadienes

✍ Scribed by Pearson, William H.; Lin, Ko Chung; Poon, Yam Foo


Book ID
126938957
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
933 KB
Volume
54
Category
Article
ISSN
0022-3263

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Stannes in synthesis: A new route to 2-s
✍ Yoshio Ueno; Hiroshi Sano; Seiichi Aoki; Makoto Okawara πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 202 KB

a-(Hydroxymethyl)allyl tolylsulfones reacted with tributyltin hydride in the presence of azobisisobutyronitrile(AIBN) in refluxing benzene to give a allyltin derivatives which subsequently gave 2-substituted-1,3-butadienes upon distillation in good yield.