✦ LIBER ✦
Stannes in synthesis: A new route to 2-substituted-1,3-butadienes via stereoselective allyltin formation under homolytic conditions
✍ Scribed by Yoshio Ueno; Hiroshi Sano; Seiichi Aoki; Makoto Okawara
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 202 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
a-(Hydroxymethyl)allyl tolylsulfones reacted with tributyltin hydride in the presence of azobisisobutyronitrile(AIBN) in refluxing benzene to give a allyltin derivatives which subsequently gave 2-substituted-1,3-butadienes upon distillation in good yield.