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A stereocontrolled total synthesis of (±)-norzizanone

✍ Scribed by Lokesh Chandra Pati; Arnab Roy; Debabrata Mukherjee

Book ID
104211406
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
77 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

A stereocontrolled total synthesis of (±)-norzizanone 1 has been efficiently accomplished involving base-induced rearrangement of the mesylate 17 as the key step. Aryl participated intramolecular cyclisation of the bromophenol 11 provided the tricyclic dienone 12, which was stereoselectively converted into the mesylate 17.

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