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A stereocontrolled total synthesis of (.+-.)-hirsutic acid C

โœ Scribed by Trost, Barry M.; Shuey, Charles D.; DiNinno, Frank


Book ID
120891270
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
300 KB
Volume
101
Category
Article
ISSN
0002-7863

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Total synthesis of d1-hirsutic acid
โœ Hisanobu Hashimoto; Kazuo Tsuzuki; Fujio Sakan; Haruhisa Shirahama; Takeshi Mats ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 170 KB

Although the skeleton of hirsutic acid [L)l,', a highly oxygenated fungal sesquiterpenoid, has already been synthesized 3,4 , the total synthesis of the acid has remained unsettled, because of the difficulty of constructing the densely functionalized system. Herein we describe a stereospecific conv