Total synthesis of d1-hirsutic acid
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Hisanobu Hashimoto; Kazuo Tsuzuki; Fujio Sakan; Haruhisa Shirahama; Takeshi Mats
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Article
📅
1974
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Elsevier Science
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French
⚖ 170 KB
Although the skeleton of hirsutic acid [L)l,', a highly oxygenated fungal sesquiterpenoid, has already been synthesized 3,4 , the total synthesis of the acid has remained unsettled, because of the difficulty of constructing the densely functionalized system. Herein we describe a stereospecific conv