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A short formal total synthesis of (±)-hirsutic acid

✍ Scribed by Revol, Guillaume; Fuchs, Christian; Zard, Samir Z.


Book ID
120663444
Publisher
NRC Research Press
Year
2012
Tongue
French
Weight
184 KB
Volume
90
Category
Article
ISSN
0008-4042

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Total synthesis of d1-hirsutic acid
✍ Hisanobu Hashimoto; Kazuo Tsuzuki; Fujio Sakan; Haruhisa Shirahama; Takeshi Mats 📂 Article 📅 1974 🏛 Elsevier Science 🌐 French ⚖ 170 KB

Although the skeleton of hirsutic acid [L)l,', a highly oxygenated fungal sesquiterpenoid, has already been synthesized 3,4 , the total synthesis of the acid has remained unsettled, because of the difficulty of constructing the densely functionalized system. Herein we describe a stereospecific conv