Stereoselective reduction of conjugated homopropargylic alcohols 1 followed by an elimination reaction, allows an efficient approach to stereodefined (E,E,E)-chlorotrienes. The interest of these chlorotrienes was illustrated by a stereocontrolled synthesis of navenone B and all E conjugated polyenes
A stereocontrolled method for the synthesis of conjugated polyenes
✍ Scribed by Benoit Crousse; Mouâd Alami; Gérard Linstrumelle
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 182 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
it to the synthesis of pseudoguaianolides and steroids. I We Claisen rearrangement and ene reaction applied in tandem and oxy-ene products during the course of the rearrangement of v reaction's potential for rapid assembly of functionalized [3 We have previously described the tandem Cope-Claisen rea