A Stable σ/π-Organometallic Radical of Vanadium: (η5-C5Me4Et)2 VCCC6H2Me3
✍ Scribed by Doz. Dr. Frank H. Köhler; Dipl.-Chem. Wolfram Prössdorf; Dr. Ulrich Schubert; Dietmar Neugebauer
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 247 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
Cyclopentadienyl and its derivatives (Cp ligands) are among the most extensively utilized p ligands in organometallic chemistry. In most organometallic reactions of transitionmetal complexes, the h 5 -Cp ligand plays the role of a spectator that stays tightly bound in h 5 fashion to the metal center
The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4