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A Spin-Crossover Cluster of Iron(II) Exhibiting a Mixed-Spin Structure and Synergy between Spin Transition and Magnetic Interaction

✍ Scribed by Da-Yu Wu; Osamu Sato; Yasuaki Einaga; Chun-Ying Duan


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
424 KB
Volume
121
Category
Article
ISSN
0044-8249

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## Abstract A dinuclear iron(II) complex containing the new pyridyl bridging ligand, 2,5‐di(2′,2′′‐dipyridylamino)pyridine (ddpp) has been synthesised and characterised by single‐crystal X‐ray diffraction, magnetic susceptibility and Mössbauer spectral methods. This compound, [Fe~2~(ddpp)~2~(NCS)~4