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A Spectroscopic and Mechanistic Study of the Enolization and Diol Formation of Hexafluoroacetylacetone in the Presence of Water and Alcohol

โœ Scribed by Aygen, Sitke ;van Eldik, Rudi


Publisher
Wiley (John Wiley & Sons)
Year
1989
Tongue
English
Weight
411 KB
Volume
122
Category
Article
ISSN
0009-2940

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By virtue of their high polarity, a wide variety of allylic metal and metalloid (e.g., B, Si, Sn) complexes can serve as nucleophilic reagents toward carbonyl compounds; [1] some allylations can be successfully performed even in the presence of water under Barbier conditions. [2] On the other hand,