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A soluble manganese(IV) intermediate in the permanganate oxidation of uracils

✍ Scribed by László I. Simándi; Miklós Jáky; Fillmore Freeman; Charles O. Fuselier; Elaine M. Karchefski

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
228 KB
Volume
31
Category
Article
ISSN
0020-1693

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✦ Synopsis

The permanganate oxidation of alkencs is generally believed to occur via an intermediate cyclic hypomanganate ester both in alkaline [ 1, 21 and acidic media [3-51. Two types of intermediates have been detected in these reactions, viz. manganese(II1)

[4-

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