A simulation of kinetics and chain length distribution of styrene FRP and ATRP: Chain-length-dependent termination
โ Scribed by Mohammad Najafi; Hossein Roghani-Mamaqani; Vahid Haddadi-Asl; Mehdi Salami-Kalajahi
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 465 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0730-6679
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๐ SIMILAR VOLUMES
A numerical procedure is developed which allows taking into account the chain length dependence of the termination and propagation constants for calculating molecular weight distributions (MWDs) formed under free-radical polymerization initiated by an arbitrary sequence of laser pulses. The law whe
It is shown that the (established) method of deriving chain-length distributions from propagation probabilities is not fully consistent with the Poissonian character of chain propagation if termination is chain-length dependent: the fluctuation of chain propagation leads to somewhat lower radical co