A Simplified Mean Spherical Approximation for the Prediction of the Osmotic Coefficients of Aqueous Electrolyte Solutions
β Scribed by Sun, Tongfan; Lenard, Jean-Louis; Teja, Amyn S.
- Book ID
- 120589513
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 766 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The Helmholtz free energy of ionic solutions is calculated in the dressed-ion theory (DIT) using a Gibbs-Helmholtz relation. The obtained expression naturally takes into account the occurrence of a process of renormalization of charges and screening length in the bulk which is described by means of
Activity coefficients and thermodynamic association constants have been estimated for NaBr, NaCI, Nal, NaCIOJ, Bu,NBr, BuJNI, and BuJNC103 electrolytes in methanol by means of a tit of experimental data to theory using the unrestricted version of the mean spherical approximation. Realistic sizes for