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A Simple Thermodynamic Model for Rationalizing the Formation of Self-Assembled Multimetallic Edifices: Application to Triple-Stranded Helicates

✍ Scribed by Zeckert, Kornelia; Hamacek, Josef; Rivera, Jean-Pierre; Floquet, Sébastien; Pinto, André; Borkovec, Michal; Piguet, Claude

Book ID: 120006166
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 414 KB
Volume: 126
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja0483443

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## Abstract A thermodynamic model has been developed for quantitatively estimating cooperativity in supramolecular polymetallic [M~__m__~L~__n__~] assemblies, as the combination of two simple indexes measuring intermetallic (${I{{{\rm MM}\hfill \atop {\rm c}\hfill}}}$) and interligand (${I{{{\rm LL