A Simple Thermodynamic Model for Quantitatively Addressing Cooperativity in Multicomponent Self-Assembly Processes—Part 2: Extension to Multimetallic Helicates Possessing Different Binding Sites

A Simple Thermodynamic Model for Quantit

A Simple Thermodynamic Model for Quantitatively Addressing Cooperativity in Multicomponent Self-Assembly Processes—Part 1: Theoretical Concepts and Application to Monometallic Coordination Complexes and Bimetallic Helicates Possessing Identical Binding Sites

✍ Josef Hamacek; Michal Borkovec; Claude Piguet 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 204 KB

## Abstract A thermodynamic model has been developed for quantitatively estimating cooperativity in supramolecular polymetallic [M~__m__~L~__n__~] assemblies, as the combination of two simple indexes measuring intermetallic (${I{{{\rm MM}\hfill \atop {\rm c}\hfill}}}$) and interligand (${I{{{\rm LL