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A Simple Synthesis of 1,1-Dibromo-1a,9b-dihydrocyclopropa[l]phenanthrene.

โœ Scribed by Jennifer M. Nguyen; Dasan M. Thamattoor


Publisher
John Wiley and Sons
Year
2007
Weight
21 KB
Volume
38
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of the Side Ch
โœ Ning Yin; Guangwei Wang; Mingxing Qian; Eiichi Negishi ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 153 KB

We report herein a stereoselective synthesis of the side chains of mycolactones A (1 A) and B (1 B). These side chains 2 A and 2 B, respectively, are protected as a methoxymethyl (MOM) ether at C12 and tert-butyldimethylsilyl (TBS) derivatives at C13 and C15, and are thus ready to be used as interme