✦ LIBER ✦

A simple sum rule in raman theory

✍ Scribed by R.A. Harris; R. Mathies; A. Myers

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 264 KB
Volume: 94
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87098-5

No coin nor oath required. For personal study only.

✦ Synopsis

It is shown that in the limit of lage detuning encrry and in the absence of coordiuate dependence of the tmnsition moment, the resonance Raman amplitude for a 0

x J-" -II transition on a harmonic potential surface is proportional to (Sf + 6:)-l ,csp(-q*j-

[CJ"AV(~)/~~"]

dq, where Al'(q) is the difference between the arbitrary excited-state surface and rhc initial harmonic potential. The resonant and non-resonant detuning energies arc given by 6_ = E -hv and 6, = E + Jw. where Y is the incident laser frequency and E is the minimum separation between the potential surfaces.

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