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Comment on a sum rule for vibrational raman optical activity

โœ Scribed by P.L. Polavarapu

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
203 KB
Volume
123
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The expressions for the sum of vibrational Raman optical activity (ROA) intensities indtcate that the ROA intensity sum for chiral molecules is non-zero for those with an anisotropic electric dipole polarizability.

The non-zero sum depends upon the electric dipole, magnetic dipole and electric quadrupole polarizability components and moments of inertia at equilibrium geometry.

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