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A SIMPLE STEREOSELECTIVE METHOD FOR THE PREPARATION OF ( E )-2,5-DIMETHYL-1,3,5-HEXATRIENE

✍ Scribed by Ramadas, S. R.; Ehrencron, R.; Gielen, J. W. J.; Jacobs, H. J. C.


Book ID
120646575
Publisher
Taylor and Francis Group
Year
1981
Tongue
English
Weight
192 KB
Volume
13
Category
Article
ISSN
0030-4948

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A new synthesis of (3E, 5Z)-1.3,5-undecaniene (2) is presented. based on a Munnich addition to 1.4 decadiyne, followed by L&&r hydtogenation and H&aan elimbtadon. 'PItis "one pot" coupling of C7+C3+Cl syntbons affords 2 stereochemically pure. Following thek discovery in the essential oil of galbanum