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A simple preparative method for optically active glycidic esters

✍ Scribed by Fumio Toda; Hideaki Takumi; Kenya Tanaka

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
158 KB
Volume
6
Category
Article
ISSN
0957-4166

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✦ Synopsis

Some optically active glycidic esters were prepared by resolution through inclusion complexation with a chiral host compound, (R,R)-(-)-trans-4,5-bis(hydroxydiphenylmethyl)-2,2dimethyl-1,3-dioxacyclopentane, and its derivatives.

Optically active glycidic esters are useful synthon for various biologically active substances such as leukotriene B 4' 1 kijanolide,2 tetronolide 2 and chlorothricolide. 2 Esterification of optically active glycidic acid ~" RI_-R2=I~I--_Me: R3mH ~ RI=R3~R~Me; R2=H

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