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A simple preparation of symmetrical and unsymmetrical diarylsulfides from arenediazonium tetrafluoroborates

✍ Scribed by Giovanni Petrillo; Marino Novi; Giacomo Garbarino; Carlo Dell'Erba


Book ID
104236601
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
214 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis


The reaction between arenediazonium tetrafluoroborates and arenethiolates in Me2S0 represents a mild, efficient, and safe alternative to the Ziegler synthesis of diaryL sulfides.


πŸ“œ SIMILAR VOLUMES


Arenediazonium tetrafluoroborates as ini
✍ Marino Novi; Giovanni Petrillo; Maria Luisa Sartirana πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 French βš– 243 KB

Polymerisation of p-bromobenzenethiolate to poly(p-phenylene sulfide) is unprecedentedly achieved in DMSO by-the employment of catalytic amounts of a diazonium salt via a radical, radical-anion chain pathway. The synthesis is likewise applicable to methyl substituted polylp-phenylene sulfide)s as we