✦ LIBER ✦
Arenediazonium tetrafluoroborates as initiators in the polymerisation of haloarenethiolates. A simple and mild access to poly(arylene sulfide)s.
✍ Scribed by Marino Novi; Giovanni Petrillo; Maria Luisa Sartirana
- Book ID
- 104219494
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 243 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Polymerisation of p-bromobenzenethiolate to poly(p-phenylene sulfide) is unprecedentedly achieved in DMSO by-the employment of catalytic amounts of a diazonium salt via a radical, radical-anion chain pathway. The synthesis is likewise applicable to methyl substituted polylp-phenylene sulfide)s as well as to poly(m-phenylene sulfide). --