Thioacetals and thioketals were readily cleaved to car-bony1 compounds in excellent yields by treatment with t-butyl thionitrite at ca. 0ยฐC in acetonitrile under mild conditions. The conversion of thioketals to the ketones appears to be initiated via nitrosation on two sulfur atoms of the thioketals
A simple method of dethioacetalization
โ Scribed by Gilbert Stork; Kang Zhao
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 169 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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