## Abstract Competing firstβ and secondβorder reactions of transient molecular species (e.g., triplet states and free radicals) are a common occurrence in kinetic studies such as flash photolysis and pulse radiolysis. We have developed a method for analyzing the decay kinetics of any species (__Y__
A simple method for analysis of consecutive reactions with a second order formation and a first order decay of an intermediate
β Scribed by N. J. Matuska; R. N. Bose
- Book ID
- 111759983
- Publisher
- Springer Netherlands
- Year
- 1997
- Tongue
- English
- Weight
- 362 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0922-6168
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An isothermal heterogeneous reactor with first order kinetics is characterized by two virtual maximum efficiencies, JV"~,. and JV~,, which are readily determined from the appropriate kinetic and transport parameters. The actual efficiency of the reactor, which is related to the conversion, X, by X =
The authors have utilized a previously proposed mathematical equation (introduced originally for development of empirical equations) as a useful tool for evaluation of first-order reaction rate constants. By assigning physical significance to the parameter a, the equation can be utilized in obtainin