In Monte Carlo simulations of polymeric chains, the chains are mast often represented as spheres, or cylinders with flat ends. In this methodological paper, we adopt a representation of the chains as spherocylinders (continuous cylinders ending in semispheres). With such a representation the testing
A simple derivation of the exponent γ for Gaussian chains with excluded volume
✍ Scribed by Andrzej Kloczkowski; James E. Mark; Burak Erman
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 286 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1022-1344
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✦ Synopsis
Abstract
The exponent γ in the expression for the partition function Z ≅ μ^N^ · N^γ−1^ is derived for a Gaussian chain. The method of Ullman is adopted. Results of calculations show that for 1, 2, 3 and 4 dimensions, γ = 1, 1,25, 1,2 and 1, respectively. It is also shown that γ remains unity for all dimensions higher than four. These results are in better agreement with exact computer simulation results than the first‐order renomalization group theory calculations. The self consistency of the present method and possible improvements along the lines of the present study are discussed.
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