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A simple and scalable method to prepare 1-aza-5-chloro-5-stannabicyclo[3.3.3]undecane

✍ Scribed by Chunhua Yang; Mark S Jensen; David A Conlon; Nobuyoshi Yasuda; David L Hughes

Book ID: 104211119
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 73 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01570-7

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✦ Synopsis

A simple and scalable method for the preparation of a potentially versatile organostannane, 1-aza-5chloro-5-stannabicyclo[3.3.3]undecane (1), is described. Stannane 1 was prepared by the disproportionation of N(CH 2 CH 2 CH 2 SnBu 3 ) 3 and SnCl 4 at 70-100°C. This reaction requires the addition of water or an alcohol to proceed efficiently. Under typical conditions, 1 was isolated in 50-55% yield after a simple acid/base extraction sequence.

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