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A simple and inexpensive procedure for chloromethylation of certain aromatic compounds

โœ Scribed by Alexander McKillop; Fereidon Abbasi Madjdabadi; David A. Long

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
179 KB
Volume
24
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Reaction of a range of aromatic compounds with methoxyacetyl chloride and aluminium chloride in either nitromethane or carbon disulphide results in chloromethylation in good to excellent yield.

Chloromethylation of aromatic compounds was a very widely used reaction

for well over half a century, both on a laboratory and industrial scale, until the hazards associated with chloromethyl and dichloromethyl ether (or reagent combinations which could result in the formation of these ethers) were recognised. 192

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