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A Simple and Efficient Synthetic Route to Enantiopure Scorpionate Ligands

✍ Scribed by Antonio Otero; Juan Fernández-Baeza; Antonio Antiñolo; Juan Tejeda; Agustín Lara-Sánchez; Luis Sánchez-Barba; Margarita Sánchez-Molina; Sonia Franco; Isabel López-Solera; Ana M. Rodríguez

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
103 KB
Volume
2006
Category
Article
ISSN
1434-1948

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A Simple and Efficient Synthetic Route to Chiral Isopavines. Synthesis of (-)-O-Methylthalisopavine and (-)-Amurensinine. -The key steps in the synthesis of the title compounds (VIII) are stereoselective addition of the Grignard reagent (II) to the imines (I) and a novel one-pot double-intramolecul