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A simple and convenient method for the synthesis of 1-dialkylaminocarbothioic acid S-[(2,3-epithio)propyl] esters

✍ Scribed by Kiran Kumar; V. L. Sharma; A. K. Dwivedi

Publisher
Journal of Heterocyclic Chemistry
Year
2006
Tongue
English
Weight
99 KB
Volume
43
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

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A simple and convenient method for the synthesis of 1‐dialkylaminocarbothioic acid S‐[(2,3‐epithio)propyl] ester was developed by the reaction of 1‐dialkylaminocarbodithioic acid‐sodium salt with 1‐chloro‐2,3‐epoxypropane in water‐methanol mixture at room temperature. An intermediate was isolated and characterized, based on which a possible mechanism was proposed.

📜 SIMILAR VOLUMES

Polymer-supported reagents : a simple an
Polymer-supported reagents : a simple and efficient method for the synthesis of esters of 2,4-dichlorophenoxyacetic acid
✍ M.M. Salunkhe; M.T. Thorat; R.B. Mane; P.P. Wadgaonkar 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 141 KB

Insoluble polymer-supported nucleophilic reagent was prepared by treatment of the sodium salt of 2,4-dichlorophenoxyacetic acid with Amberlite IRA-400 (CI-form). This reagent was treated with appropriate halogen compounds in ethanol at room temperature to give the corresponding esters of 2,4-dichlor