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A Short Synthetic Route to the Calystegine Alkaloids.

โœ Scribed by Philip R. Skaanderup; Robert Madsen

Publisher
John Wiley and Sons
Year
2003
Weight
237 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract For Abstract see ChemInform Abstract in Full Text.

ChemInform Abstract: A Short Enantiosele
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A Short Enantioselective Synthetic Route to (+)-Cassiol. -Cyclohexenone derivative (VI), a key intermediate for the preparation of (+)-cassiol (VII), is synthesized starting from ฮฒ-methylpropionylacetate (I) by condensation with chiral amine (II) followed by asymmetric Michael reaction with acrolei