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A short synthesis of C-glycosyl pyrazoles and pyrroles

✍ Scribed by José L. Del Valle; Cecilia Polo; TomÁS Torroba; Stefano Marcaccini


Book ID
112131265
Publisher
Journal of Heterocyclic Chemistry
Year
1995
Tongue
English
Weight
237 KB
Volume
32
Category
Article
ISSN
0022-152X

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The Grubbs second generation ruthenium catalyst was employed for the cross metathesis between aand b-C-allyl glycosides and suitably protected L-vinyl glycines to furnish olefinic products in 57-94% yields. Hydrogenation afforded the C-glycosyl asparagines in high yield.