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A short synthesis of (±)-alloyohimbane via a thioisomünchnone based intramolecular dipolar-cycloaddition reaction

✍ Scribed by Todd M. Heidelbaugh; Bing Liu; Albert Padwa

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
173 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

Thioisomtinchnone dipoles were generated by the reaction of bromoalkenoyl chlorides with thioamides. The intramolecular dipolar-cycloaddition reaction was used for a short synthesis of the yohimbanoid alkaloid (+)-alloyohimbane.

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