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A short, enantioselective synthesis of (-)-swainsonine

✍ Scribed by Bennett, Richard B.; Choi, Jong Ryoo; Montgomery, Walter D.; Cha, Jin K.

Book ID
121755589
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
432 KB
Volume
111
Category
Article
ISSN
0002-7863

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Short step enantioselective synthesis of
Short step enantioselective synthesis of (βˆ’)-swainsonine
✍ T. Punniyamurthy; Ryo Irie; Tsutomu Katsuki πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 164 KB πŸ‘ 2 views

Recent discovery of asymmetric desymmetrization of meso-heterocycles using (R,R)-(salen)manganese complex 2 as a catalyst allowed easy access to optically active 2,3,4-trisubstituted pyrrolidines. Taking advantage of this new reaction, we could achieve the short-step synthesis of (-)-swainsonine 1.