A Short and Highly Stereoselective Synthesis of α-(2-Aminothiazolyl)-C-nucleosides.
✍ Scribed by Jean-Michel Navarre; Dominique Guianvarc'h; Audrey Farese-Di Giorgio; Roger Condom; Rachid Benhida
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 22 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
📜 SIMILAR VOLUMES
A short and highly stereoselective synthesis of squalamine (1) was accomplished in 9 steps from easily available methyl chenodeoxycholanate (2). The advanced intermediate 7α,24R-dihydroxy-cholestan-3-one (9) was synthesized by using improved dehydrogenation of 4 followed by conjugate reduction and e
Highly Stereoselective Synthesis of 2-Deoxy-α-glycosides and α-Disaccharides. -Using S-(2-deoxyglycosyl)phosphorodithioates such as (I) as glycosyl donors allows a highly diastereoselective synthesis of 2-deoxyα-glycosides [cf. (III)] and α-disaccharides such as (V). -(BIELAWSKA,
A solution of [Ru,(CO),,] (200 mg. 0.32 mmol) and freshly distilled diazocyclopentadieiie [I31 (30 pL. 0.5 mmol) in dried T H F (40 mL) was heated at reflux under nitrogen lbi irnc hour. After evaporation of the solvent. thin-layer chromatography (SiO?) of Ihc orange-rcd residue. eluting with pentan