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A series of new polyoxoanion-based inorganic-organic hybrids: (C6NO2H5)[(H2O)4(C6NO2H5)Ln(CrMo6H6O24)]·4H2O (Ln = Ce, Pr, La and Nd) with a chiral layer structure

✍ Scribed by An, Haiyan; Xiao, Dongrong; Wang, Enbo; Li, Yangguang; Xu, Lin

Book ID
120665289
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
923 KB
Volume
29
Category
Article
ISSN
1144-0546

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Open-Framework Polar Compounds: Synthesi
Open-Framework Polar Compounds: Synthesis and Characterization ofRare-Earth Polyoxometalates (C6NO2H5)2[Ln(H2O)5(CrMo6H6O24)]·0.5H2O (Ln = Ce and La)
✍ Haiyan An; Dongrong Xiao; Enbo Wang; Yangguang Li; Xinlong Wang; Lin Xu 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 173 KB

## Abstract Two unprecedented open‐framework polar compounds (C~6~NO~2~H~5~)~2~[Ln(H~2~O)~5~(CrMo~6~H~6~O~24~)]·0.5H~2~O [Ln = Ce (1), La (2); C~6~NO~2~H~5~ = pyridine‐3‐carboxylic acid], constructed from Anderson‐type polyoxo anions and rare‐earth cations, have been synthesized for the first time