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A second polymorph of (2-thiazolidinethionato)­(triphenyl­phosphine)gold(I)

✍ Scribed by Horvath, Ulrike E. I. ;Cronje, Stephanie ;Nogai, Stefan D. ;Raubenheimer, Helgard G.

Book ID
104486902
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
228 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Au(C~3~H~4~NS~2~)(C~18~H~15~P)], contains a thiazolidinethione ligand coordinated to an Au^I^ atom through the S atom. A triphenylphosphine ligand completes the linear coordination geometry around the Au atom. The compound contains two molecules in the asymmetric unit and is a polymorphic form of a previously reported structure [Grant, Forward & Fackler Jr (1996). Z. Kristallogr.
211, 483–484]. The composite molecules in the two forms exhibit nearly identical bond distances and angles.

📜 SIMILAR VOLUMES

A third polymorph of (2-thiazolidinethio
A third polymorph of (2-thiazolidinethionato)(triphenyl­phosphine)gold(I)
✍ Horvath, Ulrike E. I. ;Raubenheimer, Helgard G. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 250 KB

The title compound, [Au(C~3~H~4~NS~2~)(C~18~H~15~P)], is a third polymorphic form of a compound previously reported by Grant, Forward & Fackler Jr [__Z. Kristallogr.__ (1996). 211, 483–484]. At 100 K, the present polymorph shows triclinic symmetry, as do the other two polymorphs.