๐”– Bobbio Scriptorium
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A search for redistribution reactions of carbonium ions with boranes and alanes

โœ Scribed by Roger W. Alder; Hugh J. Gorton

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
109 KB
Volume
15
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The isoelectronic relationship between R,,B and R3C+ is frequently alluded to, although structural similarities are rare. The conjugative and hyperconjugative

๐Ÿ“œ SIMILAR VOLUMES

Evidence for a carbonium ion rearrangeme
Evidence for a carbonium ion rearrangement in the reaction of triisobutylaluminum and 1,3,3-trimethylcyclopropene
โœ Herman G. Richey Jr.; Barry Kubala; Mark A. Smith ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 212 KB

Formation of acyclic products in the reaction of triisobutylaluminum and 1,3,3trimethylcyclopropene can reasonably be ascribed to a carbonium ion rearrangement. This suggestion supports the mechanism for carbalumination of alkenes proposed by Eisch.