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A Route to a Germanium–Carbon Triple Bond: First Chemical Evidence for a Germyne

✍ Scribed by Christine Bibal; Stéphane Mazières; Heinz Gornitzka; Claude Couret


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
90 KB
Volume
40
Category
Article
ISSN
0044-8249

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Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop