A revised mechanism for third order alcoholyses of acid chlorides in aprotic solvents

✍ Scribed by Dennis N. Kevill; Fred D. Foss

• Book ID: 104224009
• Publisher: Elsevier Science
• Year: 1967
• Tongue: French
• Weight: 196 KB
• Volume: 8
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)90869-4

✦ Synopsis

It has recently been shown' that reactions of alkyl chlorofonnates with silver nitrate in acetonitrile proceed with either a rate limiting nucleophilic attack (the rate also being influenced by the partitioning of the intermediate to reactants or products) or a rate detennininq electrophilic assistance but not both simultaneously.