The sulfoxide group shows a lot of interesting stereochemical features (2). In thiane-l-oxide the axial conformation (62% of the mixture at -9OOC) is favored by 175 Cal/mole (2). Introduction of a 3,3-dimethyl grouping reverses this axial
โฆ LIBER โฆ
A remarkable consistency in conformational preference for a series of 1,3-disubstituted-2,2-dimethylpropanes
โ Scribed by Michael R. Whalon; Gilbert L. Grady; Paul McGoff; Raymond P. Domingue; C.Hackett Bushweller
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 267 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
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